Synthesis of cyclic β-silylenones via oxidative rearrangement of tertiary α-hydroxy allylsilanes wit

期刊名字：中國化學(xué)快報(bào)（英文版）
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論文作者：Xia Wu，Jian Lei，Zhen Lei Song
作者單位：Key Laboratory of Drug-Targeting of Education Ministry and Department of Medicinal Chemistry
更新時間：2022-11-28
下載次數(shù)：次

論文簡介

An oxidative rearrangement of cyclic tertiary *-hydroxy allylsilanes has been carried out in refluxing ClCH2CH2Cl with pyridinium chlorochromate (PCC). The reaction provides a convenient method to synthesize cyclic β-silylenones in modest to excellent yields.

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